Discussion on the determination method of small specific surface area below 1m2/g - Database & Sql Blog Articles

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The lower limit of the surface area measured by the low temperature nitrogen adsorption method is generally

1m

The volume of the gas adsorbate in the 2/g sample tube (standard state) minus the volume of the unadsorbed gas in the sample tube (standard state). In the case of using nitrogen as the adsorbate, the measurement of the amount of adsorption will result in a large error in the sample with a small surface area. Because the adsorption amount is small at this time, and the nitrogen saturated vapor pressure as the adsorbate at liquid nitrogen temperature is close to the atmospheric pressure, the amount of nitrogen remaining in the sample tube after the adsorption equilibrium is reached under a certain relative pressure in the experimental range. Still large, the amount of total nitrogen that is initially transferred to the sample tube (before adsorption) is comparable and not easily calibrated. The biggest advantage of the ruthenium adsorption method is that the saturated vapor pressure of ruthenium at liquid nitrogen temperature is only about 2 mmHg. Therefore, in the measurement range of the adsorption isotherm, the unadsorbed ruthenium remaining in the dead space after the adsorption equilibrium is reached. The change in gas volume is large and can be measured accurately, so helium is suitable for the determination of low specific surface solids.

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